FUJITSU QUALITY LABORATORY

AES, SAM

Auger Electron Spectroscopy

In scanning Auger Microprobe system solid-state specimen is bombarded with finely focused electron beam to eventually obtain Auger electrons. Auger electrons from only the outermost few atomic layers are emitted from the specimen without energy loss, and contribute to the AES (Auger Electron Spectroscopy) peaks in a spectrum (except for H,He).

With AES technology, lateral distributions of elements at the surface, so-called Auger maps can be obtained. Also, the combination of two technologies; AES measurements and sputter etching, allows as to obtain depth profile.
AES is the technology that greatly contributes to problem solution - problems such as corrosion, discoloration, junction, thin layer or foreign material in metal or IC.

Equipment

SAM

PHI Model 680
(Scanning Auger Nanoprobe System)

Example

Element Analysis of Abnormal area in Metal Surface

 Secondary electron image at low magnifications
Secondary electron image of metal surface at low magnifications
 Secondary electron image at high magnification
Secondary electron image of metal surface at high magnifications
 Qualitative analysis result of abnormal/normal area in metal surface.
Auger spectrum of abnormal/normal area of metal surface

Cl and N are detected in abnormal area, hence these contaminant foreign element mixed and adhered in other process.



Element distribution - Contaminated trace surface

 Secondary electron image of trace pattern and distribution of Carbon.
Carbon mapping and Secondary electron image of trace pattern

Trace pattern surface is contaminated with organic substance mainly consists of carbon



Depth direction analysis on Solder bump surface

 Secondary electron image of normal bump
Secondary electron image of normal bump
 Secondary electron image of dented bump
Secondary electron image of dented bump
 Sputter depth profiles of solder bump surfaces
Depth profile of solder bump surface

Ther dented bump was proved to have thicker oxide film on the surface, than the normal bump has .



Line profile and Auger map on cross section of solder bump

Secondary electron image of cross section
 Line profile on the cross section
Line profile of polished cross section surface

 Auger map on the cross section
Element mapping of polished cross section surface

In the interface between Ni and solder, layer of Ni-Sn alloy and segregating P are observed.


Analysis of interface processed with Micro capsule type anisotropic conductive adhesive

Analysis result of interface with anisotropic conductive adhesive